| Champions League - Kvinder | 2020/12/04 19:00 | Xiaona Shan v Maria Xiao | W | 3-0 |
| Champions League - Kvinder | 2022/11/29 17:05 | Xiaona Shan v Dora Madarasz | L | 2-3 |
| WTT Feeder Düsseldorf - Kvinder | 2022/11/25 17:10 | Natalia Bajor v Xiaona Shan | W | 0-4 |
| WTT Feeder Düsseldorf - Kvinder | 2022/11/25 09:45 | Miyu Nagasaki v Xiaona Shan | L | 3-2 |
| WTT Feeder Düsseldorf - Kvinder | 2022/11/24 11:40 | Yuan Wan v Xiaona Shan | L | 3-2 |
| WTT Feeder Düsseldorf - Kvinder | 2022/11/23 16:05 | Sofia Xuan Zhang v Xiaona Shan | W | 2-3 |
| Europa - Champions League - Kvinder | 2022/11/18 19:30 | Xiaona Shan v Andreea Dragoman | W | 3-1 |
| Champions League - Kvinder | 2022/11/18 17:25 | Xiaona Shan v Tania Plaian | L | 1-3 |
| Champions League - Kvinder | 2022/11/12 18:35 | Andreea Dragoman v Xiaona Shan | W | 0-3 |
| Champions League - Kvinder | 2022/11/29 17:20 | Maria Xiao v Ho Ching Lee | W | 3-1 |
| WTT Feeder Düsseldorf - Kvinder | 2022/11/23 15:25 | Maria Xiao v Hyobin Yoon | L | 2-3 |
| Champions League - Kvinder | 2022/11/09 16:55 | Andreea Dragoman v Maria Xiao | W | 1-3 |
| WTT Contender Novo Gorica Women | 2022/11/01 18:00 | Maria Xiao v Camille Lutz | L | 2-3 |
| WTT Contender Novo Gorica Women | 2022/11/01 08:30 | Maria Xiao v Magdalena Sikorska | W | 3-0 |
| EM - Kvinder | 2022/08/18 14:55 | Maria Xiao v Margaryta Pesotska | L | 2-4 |
| EM - Kvinder | 2022/08/17 10:55 | Maria Xiao v Franziska Schreiner | W | 4-3 |
| WTT Star Contender Budapest Women Quals | 2022/07/11 18:30 | Chengzhu Zhu v Maria Xiao | L | 3-1 |